Observation of Pure Rotational Spectra of trans-, and cis-HOCO/DOCO

Details Observation of Pure Rotational Spectra of trans-, and cis-HOCO/DOCO Observation of Pure Rotational Spectra of trans-, and cis-HOCO/DOCO

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confemi02o&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

Physics

Radicals And Ions

Scientific paper

Rotational spectra of trans-, cis-HOCO and DOCO have been observed using an Fourier transform microwave(FTMW) spectrometer and the FTMW-mmw-DR technique. The cis-conformer was observed for the first time in the gas phase. The HOCO radical was produced in a supersonic jet by discharging a gas mixture of CO and H2O diluted in Ar. The molecular constants including the hyperfine coupling constants have been precisely determined. The determined r_0 structure of the two conformers are consistent with those of ab initio calculations. The fermi constants of the two conformers indicate that the spin densities on the hydrogen nuclei are different between the two conformers.

Affiliated with

Also associated with

No associations

Rating

Observation of Pure Rotational Spectra of trans-, and cis-HOCO/DOCO does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Observation of Pure Rotational Spectra of trans-, and cis-HOCO/DOCO, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Observation of Pure Rotational Spectra of trans-, and cis-HOCO/DOCO will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-1591030