Observation of OH Meinel (7, 4) P(N-double-prime = 13) transitions in the night airglow

Physics

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Hydroxyl Emission, Molecular Energy Levels, Molecular Rotation, Nightglow, Vibrational Spectra, Atmospheric Composition, Infrared Spectroscopy, Michelson Interferometers

Scientific paper

Improved spectral measurements of the OH Meinel Delta-v =3 night airglow emissions have revealed unexpectedly intense transitions from high rotational levels. The example selected for this communication involves the previously unreported P(N-double-prime = 13) transitions in the OH M (7, 4) band. Under the extant conditions, the column emission rates associated with these new features exceeded by factors of about 10,000 those expected on the basis of the assumption of rotational-kinetec equilibrium for the v-prime = 7 rotational manifold. The key observations are presented and some of the implications are discussed.

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