Observation of high-n Rydberg series (n is greater than 7 and less than 40) of the H3 molecule

Details Observation of high-n Rydberg series (n is greater than 7 and less than 40) of the H3 molecule Observation of high-n Rydberg series (n is greater than 7 and less than 40) of the H3 molecule

Jan 1986

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1986phrvl..56...42h&link_type=abstract

Physical Review Letters (ISSN 0031-9007), vol. 56, Jan. 6, 1986, p. 42-45.

Physics

51

Autoionization, Hydrogen, Molecular Excitation, Rydberg Series, Triatomic Molecules, Vibrational Spectra, Charge Exchange, Ground State, Ionization Potentials, Metastable State, Quantum Numbers

Scientific paper

Four series of Rydberg states converging to vibrationally excited H3(+) have been excited from long-lived levels of H3 in a fast (1.5 keV) molecular beam and have been observed to autoionize to H3(+) + e. A fifth Rydberg series converging to H3(+) in its ground vibrational state has been detected through field ionization. A first analysis of the ionization potentials, quantum defects, and the nature of the long-lived species of H3 is presented.

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