O2 continuum: A possible explanation for the discrepancies between measured and modeled shortwave surface irradiances

Physics

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Atmospheric Composition And Structure: Transmission And Scattering Of Radiation, Atmospheric Composition And Structure: Instruments And Techniques

Scientific paper

Ground based solar spectra between 1 and 5 μm (10,000 and 2000cm-1) have been obtained with a new, absolutely calibrated spectrometer. These spectra have sufficient spectral resolution (2cm-1) to allow atmospheric absorption lines to be distinguished from underlying continuum absorption. Continuum absorption due to O2 has been identified around 1.06 μm (9366cm-1), 1.27 μm (7882cm-1), and 1.6 μm (6326cm-1). These continuum absorptions are not included in the HITRAN database. Similar continuum absorption should be present around the 0.762 μm (13121cm-1) and 0.688 μm (14525cm-1) bands of O2.

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