Nonadiabatic corrections to rovibrational levels of H$_2$

Details Nonadiabatic corrections to rovibrational levels of H$_2$ Nonadiabatic corrections to rovibrational levels of H$_2$

2008-11-26

arxiv.org/abs/0811.4355v2

Physics

Chemical Physics

14 pages

Scientific paper

The leading nonadiabatic corrections to rovibrational levels of a diatomic molecule are expressed in terms of three functions of internuclear distance: corrections to the adiabatic potential, the effective nuclear mass, and the effective moment of inertia. The resulting radial Schr\"odinger equation for nuclear motion is solved numerically yielding accurate nonadiabatic energies for all rovibrational levels of H$_2$ molecule in excellent agreement with previous calculations by Wolniewicz.

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