Non-Ritzian Nature of the 3S Terms of Mercury

Details Non-Ritzian Nature of the 3S Terms of Mercury Non-Ritzian Nature of the 3S Terms of Mercury

Jul 1933

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1933natur.132..139w&link_type=abstract

Nature, Volume 132, Issue 3325, pp. 139 (1933).

Physics

Scientific paper

AT the suggestion of Dr. A. G. Shenstone, a precise determination of the energy values of the 3S terms as well as of the 3D terms of mercury iodide (HgI) has been made. The light from a beam of mercury vapour diffusing from a mercury arc through a slit in the iron anode was examined by means of a Hilger E1 instrument. This light being rich in higher series members yielded values of the 3S terms up to 193S. The plot of the quantum excess (n*-n) of the terms against the term value departed considerably from a straight line relation, indicating that the terms cannot be represented by a simple Ritz formula.

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