Non-adiabatic approach to the asymmetry of pressure broadened spectral lines.

Details Non-adiabatic approach to the asymmetry of pressure broadened spectral lines. Non-adiabatic approach to the asymmetry of pressure broadened spectral lines.

Apr 1997

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1997jqsrt..57..551c&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 57, issue 4, pp. 551-557

Physics

12

Line Broadening: Spectral Lines

Scientific paper

A semi-classical formula for the asymmetry of the profile of pressure broadened spectral lines, which takes into account non-adiabatic processes is derived. The resultant spectrum is shown to be given as a linear combination of the Lorentzian and dispersion profiles. The line profile asymmetry can be evaluated in cases when the degeneracy of both the initial and final states is important.

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