New sets of experimental wavenumber values for triplet-triplet rovibronic transitions of $H_2$ and $D_2$

Details New sets of experimental wavenumber values for triplet-triplet rovibronic transitions of $H_2$ and $D_2$ New sets of experimental wavenumber values for triplet-triplet rovibronic transitions of $H_2$ and $D_2$

2010-11-12

arxiv.org/abs/1011.2917v2

Physics

Chemical Physics

3 pages, The 21st International Conference on High Resolution Molecular Spectroscopy, Pozna\'n, Poland, September 7-11, 2010,

Scientific paper

New sets of experimental wavenumber values for triplet-triplet rovibronic transitions of $H_2$ and $D_2$ for visible part of spectrum ($400 \div 700$ nm) have been obtained. The digital intensity registration providing a linear response of the detector gave us the opportunity of digital deconvolution of the recorded line profiles. For line centers that made it possible to reach an accuracy ($< 0.0006$ nm) limited only by selfconsistency of various wavenumber standards. New sets of wavenumber values were obtained with accuracy $0.006 \div 0.05$ cm$^{-1}$.

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