New measurements of self broadening and shift of ammonia lines

Computer Science

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Ammonia, Electron Transitions, Laser Spectroscopy, Pressure Broadening, Spectral Line Width, Dipole Moments, Molecular Collisions, Semiconductor Lasers, Vibrational Spectra

Scientific paper

Pressure broadening and shift measurements are presented for transitions of the nu sub 2 = 1s-0a band, the nu sub 2 = 2s-1a band and the 1a(nu sub 4)-1a(nu sub 2) band ammonia lines. The measurements were made with diode-laser spectroscopy. The results are compared with those obtained using the Anderson (1949)-Tsao-Curnutte (1962) approximation, showing satisfactory agreement. Problems associated with incomplete knowledge of vibrational-transition dipole moments are examined.

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