New cross sections for the absorption of near ultraviolet radiation by nitrous oxide /N2O/

Physics

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Absorption Cross Sections, Atmospheric Composition, Near Ultraviolet Radiation, Nitrous Oxides, Ultraviolet Absorption, Photolysis, Stratosphere Radiation, Tropospheric Radiation

Scientific paper

A re-investigation of the ultraviolet absorption spectrum of nitrous oxide (N2O) agrees with previous results in the range 210 to 235 nm, but contrary to previous results it indicates a vanishingly small cross section above 260 nm. The absence of the relatively long wave length absorption implies a negligible rate of photolysis of nitrous oxide in the troposphere. These results plus the previously estimated atmospheric mean residence times of N2O indicate that there is a large, unknown tropospheric sink for nitrous oxide.

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