Nature of the impactor at the K/T boundary: clues from Os, W and Cr isotopes.

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We measured the isotope composition of Os, W and Cr in K/T boundary sediments of three marine sites (Stevns Klint, Caravaca and Bidart) to determine the nature of the bolid that impacted the Earth 65 Myrs ago. We also analysed Ni-rich cosmic spinels, because they are thought to keep the signature of the impactor. The low REE content in spinels precludes indeed the hypothesis of a mixing with more than 10% of terrestrial material. The Os and W enrichment at the K/T boundary could be explained by a scavenging of chalcophile elements at the time of sulfide precipitation. The 187Os/186Os ratio of the K/T sediments is higher than the ratio of any kind of meteorites. On top of a possible mixing with surrounding sediments, we suggest that the boundary contained more Re in the past (lost since that time by alteration and oxidation) and that the Os isotope ratio is in fact disturbed. On each of the three sites, the boundary itself does not present any tungsten isotopic anomaly. The most likely interpretation is that the extraterrestrial material is diluted enough into the sediments so that the isotopic signature has been erased. Spinels show a small deficit of (0.34±0.9) ɛ in 182W. The large error bar precludes any clear conclusion whether or not a meteoritic signature is really present. If the spinels really carry an extraterrestrial signature as expected, their W composition is in favour of an ordinary chondrite. All K/T samples (sediments and spinels) are apparently depleted in 53Cr by about 0.5 ɛ (after renormalization of 54Cr to the terrestrial value) whereas ordinary chondrites display an excess of about 0.5 ɛ. Among meteorites, only carbonaceous chondrites present a negative value for the 53Cr/52Cr ratio relative to the terrestrial value. As more than 90% of the Cr present in spinels is of extraterrestrial origin, the Cr isotopes unambiguously show that the K/T impactor was a carbonaceous chondrite. These isotopic results also confirm the extraterrestrial origin of spinels. The W isotope composition of the spinels does not fully agree with the conclusion of a carbonaceous chondrite, but a refined measurement is required to discuss this discrepancy in more details.

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