Nature of Hydrogen Bond in Water

Details Nature of Hydrogen Bond in Water Nature of Hydrogen Bond in Water

2012-02-14

arxiv.org/abs/1202.3035v1

Ukrainian Journal of Physics, 2012, Vol. 57, no. 2, pp. 113--117 (www.ujp.bitp.kiev.ua)

Physics

Chemical Physics

Scientific paper

The work is devoted to the investigation of physical nature of H-bond. The H-bond potential $\Phi_{H} (r,\Omega)$ is studied as an irreducible part of the interaction energy of water molecules. It is defined as a difference between generalized Stillinger-David potential and the sum of dispersive and multipole interaction potentials. Relative contribution of $\Phi_{H} (r,\Omega)$ to intermolecular potential does not exceed (10\div15)%.

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