N/2/2P fluorescence from scattering of N/2/2sigma/g/ photoelectrons

Physics

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Electron Scattering, Fluorescence, Molecular Excitation, Nitrogen, Photoelectrons, Diatomic Molecules, Kinetic Energy, Luminous Intensity

Scientific paper

Photoabsorption spectroscopy was used to study N(2)2P fluorescence intensity as a function of incident photon energy between 40 and 70 eV and at pressures of a few torr. A structure was observed near 52.2 eV: this feature is attributed to the scattering of photoelectrons originating from the N(2)2sigma(g) molecular orbital with a binding energy of about 37.7 eV. The kinetic energy of these photoelectrons corresponds to the peak of the 2P excitation cross section at 14.5 eV

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