Mössbauer spectroscopic analysis of two similar meteorites, Allende and Axtell.

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Fe-containing phases were investigated by Mössbauer spectroscopy in these two members of the meteorite group CV3 carbonaceous chondrites. Axtell recently became available to researchers, and although at first suspected of being a piece of the well-studied Allende^1, it does differ in some radiochemical details^2. The Mössbauer spectra of the two meteorites are also strikingly similar, showing barely a trace of ferromagnetic phases and a predominant paramagnetic doublet characteristic of Fe^2+ ion in the silicate mineral olivine. Both meteorites in addition show doublets for lesser amounts of Fe^3+ phases, presumably olivine oxidation products, such as sheet silicates or Fe hydroxides. These Fe^3+ doublets differ considerably between the two meteorites, and so provide further evidence that Axtell is distinct from Allende. Although Fe^3+ content in meteorites is correlated with C-14 terrestrial age on a thousand- year time scale, Allende is known to have fallen in 1969, so its Fe^3+ content probably indicates preterrestrial weathering. Axtell's terrestrial age is uncertain, but probably around 100 years^2. Thus Axtell also likely experienced an oxidative environment during its pre-fall history, and the two meteorites probably come from similar parent bodies. ^1Oliver et al Meteoritics 19 (1984) 25. ^2Simon et al., ibid. 30 (1995) 42. abstract.

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