Molecular diffusion and the sedimentary environment: results from the in situ determination of whole sediment diffusion coefficients

Physics

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Scientific paper

A dialysis technique has been developed from which whole sediment diffusion coefficients that include the effect of microbially-mediated reactions can be determined in situ . Application of the technique shows that the diffusion of both dissolved sulphate and total dissolved CO 2 (transported primarily as bicarbonate) is related to the changing porosity of a fine-grained marine sediment. Added to this, the transport of dissolved sulphate is significantly affected by the microbial reduction of the pool available for diffusion. In contrast, the diffusion of a far larger pool of total dissolved CO 2 is not noticeably affected by microbial activity.

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