Molecular conformations of triton X 114 in the presence of a small amount of water

Details Molecular conformations of triton X 114 in the presence of a small amount of water Molecular conformations of triton X 114 in the presence of a small amount of water

Apr 1989

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1989phla..136..230z&link_type=abstract

Physics Letters A, Volume 136, Issue 4-5, p. 230-232.

Physics

Scientific paper

The viscosity of the binary system Triton X 114-water and the self-diffusion of the detergent molecules of Triton X 114 have been determined experimentally in the region of small water concentrations (0-10 wt% of water). The temperature was varied from 10 to 50°C in steps of 5°C. The self-diffusion was measured by means of the NMR method. The viscosity of the samples was determined by an efflux viscosimeter. A deviation of the experimentally obtained temperature trend of the viscosity and of the molecular mobility from the theoretical expected exponential dependence was found. This may be due to the building of dimers from the detergent molecules, whose number increases in the low temperature interval.

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