Modulated conjugation as a means for attaining a record high intrinsic hyperpolarizability

Physics – Chemical Physics

Scientific paper

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4 pages, 2 figures

Scientific paper

10.1364/OL.32.000059

We report on a series of chromophores that have been synthesized with a
modulated conjugation path between donor and acceptor. Hyper-Rayleigh
scattering measurements of the best molecule show an enhanced intrinsic
hyperpolarizability that breaches the apparent limit of all previously studied
molecules.

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