Modeling Study of the Low-Temperature Oxidation of Large Methyl Esters

Details Modeling Study of the Low-Temperature Oxidation of Large Methyl Esters Modeling Study of the Low-Temperature Oxidation of Large Methyl Esters

2009-04-22

arxiv.org/abs/0904.3536v1

Physics

Chemical Physics

European Combustion Meeting 2009, Vienne : Autriche (2009)

Scientific paper

This study focuses on the automatic generation by the software EXGAS of kinetic models for the oxidation of large methyl esters using a single set of kinetic parameters. The obtained models allow to well reproduce the oxidation of n-decane / methyl palmitate mixture in a jet-stirred reactor. This paper also presents the construction and a comparison of models for methyl esters from C7 up to C17 in terms f conversion in a jet-stirred reactor and of ignition delay time in a shock tube. This comparison study showed that methyl esters larger than methyl octanoate behave similarly and have very close reactivities.

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