Microprobe analyses of rare earth element fractionation in meteoritic minerals

Physics

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Scientific paper

Two meteorites were analyzed by PIXE with the Los Alamos nuclear microprobe. The enstatite achondrite Pen~a Blanca Spring and the ordinary chondrite St Severin were chosen as likely candidates for use in 244Pu (t1/2 = 82 my) cosmochronology and geochronology. These applications require the meteoritic minerals to have unfractionated actinides and lanthanides relative to ``cosmic'' elemental abundance ratios. The PIXE analyses produced evidence of actinide-lanthanide fractionation in Pen~a Blanca Spring oldhamite (CaS) whereas the St Severin phosphates, whitlockite and chlorapatite, do not exhibit this fractionation.

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