Metal-silicate-water reaction under high pressure. II. Partition of Fe, Ni and Co between metal and silicate

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Scientific paper

The systems (Fe, Ni)-silicate-water, (Fe, Co)-silicate-water and (Fe, Ni)-silicate-water-sulfur were investigated at around 5 GPa and 1000-1500°C by using a tetrahedral-anvil and cubic-anvil high-pressure apparatus. The quenched samples showed the coexistence of olivine, pyroxene and metal. The distribution behavior of Fe, Ni and Co between metal-olivine and metal-pyroxene was measured in these quenched samples. The observed values of apparent partition coefficients, K'(Fe-Ni) and K'(Fe-Co), were approximately 40-100 and 10-30, respectively. These values are 10-100 times larger than the estimated value for the Earth's core and mantle, and would indicate that the Earth could not be in equilibrium as a total system. To explain the observed transition metal abundance in the Earth, it is necessary to consider the accretion process and the core formation processes in the partially molten layer of the proto-Earth.

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