Mechanism of the Electroreduction of Complexes of the Type [M (NH3)5X]n+

Physics

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THE effect of various anions upon the reduction of [Co(NH3)5X]3+ at the dropping mercury electrode was reported recently by Vlček and Kůta1. They explained the generation of the electrochemically active species in terms of a bimolecular substitution process that was proposed earlier2 and has since been the subject of correspondence between Dr. Vlček and one of us (G. W. W.).

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