Measurements of the NO2 absorption cross-section from 42,000 cm-1 to 10,000 cm-1 (238-1000 nm) at 220 K and 294 K.

Details Measurements of the NO2 absorption cross-section from 42,000 cm-1 to 10,000 cm-1 (238-1000 nm) at 220 K and 294 K. Measurements of the NO2 absorption cross-section from 42,000 cm-1 to 10,000 cm-1 (238-1000 nm) at 220 K and 294 K.

May 1998

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1998jqsrt..59..171v&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 59, issue 3-5, pp. 171-184

Computer Science

131

Laboratory Spectra: Molecular Data

Scientific paper

The NO2 absorption cross-section has been measured from 42,000 to 10,000 cm-1 (238-1000 nm) with a Fourier transform spectrometer (at the resolution of 2 cm-1, 0.01 nm at 240 nm to 0.2 nm at 1000 nm) and a 5 m temperature controlled multiple reflection cell. The uncertainty on the cross-section is estimated to be less than 3% below 40,000 cm-1 (λ > 250 nm) at 294 K, 3% below 30,000 cm-1 (λ > 333 nm) at 220 K, but reaches 10% for higher wavenumbers. Temperature and pressure effects have been observed. Comparison with data from the literature generally shows a good agreement for wavenumbers between 37,500 and 20,000 cm-1 (267-500 nm). Outside these limits, the difference can reach several percent.

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