Measurements of temperature-dependent argon-broadened half-widths of H2O transitions in the 7117 cm-1 region.

Physics

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Water Vapor: Infrared Spectra, Water Vapor: Laboratory Spectra, Water Vapor: Absorption Spectra, Water Vapor: Line Profiles, Water Vapor: Line Broadening

Scientific paper

A distributed-feedback InGaAsP diode laser has been used to perform spectrally resolved measurements of H2O transitions near 7117 cm-1. Line shape analyses of the recorded absorption spectra yielded the temperature dependent Ar-broadened half-widths. Room-temperature (296 K) half-widths for four transitions were determined with an uncertainty of +7%/-5%. Temperature exponents for three of these transitions were determined over the range of 296-473 K with an uncertainty of ±7%.

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