Measurements of argon-, helium-, hydrogen-, and nitrogen-broadened widths of methane lines near 9000 per cm

Physics

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Infrared Spectra, Methane, Pressure Broadening, Spectral Line Width, Vibrational Spectra, Ambient Temperature, Argon, Fourier Transformation, Helium, Hydrogen, Line Spectra, Nitrogen, Planetary Atmospheres, Spectral Resolution

Scientific paper

Pressure-broadened widths of rotational-vibrational lines in CH4 have been measured at very high spectral resolution in the R-branch of the 3nu3 overtone. The broadening gases were Ar, He, H2, and N2. Results are presented as averages for J-multiplets at ambient temperature. The overall values (per cm per atm) for these R-branch lines are 0.0651 (CH4-Ar), 0.0508 (CH4-He), 0.0728 (CH4-H2), and 0.0715 (CH4-N2).

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