Measurements of anomalous atmospheric absorption in the wavenumber range 4-15 per cm

Physics

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Absorption Spectra, Atmospheric Attenuation, Electromagnetic Absorption, Temperature Effects, Water Vapor, Absorptivity, Acoustic Velocity, Atmospheric Moisture, Infrared Radiation, Molecular Spectra, Optical Equipment, Signal To Noise Ratios, Temperature Measurement

Scientific paper

Field measurements have been made of atmospheric absorption in the wavenumber range (4-15)/cm, using a 200-m horizontal transmission path at a resolution of 0.2/cm. The results are compared with theoretical spectra based on water-vapor monomer absorption, and anomalous absorption spectra are presented. There is support from some preliminary laboratory work. A binding energy of between 0.4 and 0.8 electron volts per molecule is derived for the water-vapor complex responsible for the absorption.

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