Measurement of the ionization potential of triatomic hydrogen

Details Measurement of the ionization potential of triatomic hydrogen Measurement of the ionization potential of triatomic hydrogen

Oct 1988

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1988phrva..38.3425h&link_type=abstract

Physical Review A - General Physics, 3rd Series (ISSN 0556-2791), vol. 38, Oct. 1, 1988, p. 3425-3429.

Physics

General Physics

38

Hydrogen, Ionization Potentials, Molecular Ions, Triatomic Molecules, Photoabsorption, Rydberg Series, Vibrational Spectra

Scientific paper

The d Rydberg series of H3 converging to the lowest rotational level of ortho-H3(+) has been detected for n values ranging from 27 to 100 using field ionization. Extrapolation of the Rydberg series yields an ionization potential of 29,562,6/cm + or - 0.5/cm. The amplitudes of the excitation spectra reveal the interaction between the H3(+) cores with N(+) = 1 and 3 via l uncoupling of the d electron, as well as window resonances from interlopers belonging to vibrationally excited H3(+) cores.

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