Mathematical expression for the O /1D/ quantum yields from the O3 photolysis as a function of temperature /230-320 K/ and wavelength /295-320 nm/

Details Mathematical expression for the O /1D/ quantum yields from the O3 photolysis as a function of temperature /230-320 K/ and wavelength /295-320 nm/ Mathematical expression for the O /1D/ quantum yields from the O3 photolysis as a function of temperature /230-320 K/ and wavelength /295-320 nm/

Mar 1978

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1978georl...5..191m&link_type=abstract

Geophysical Research Letters, vol. 5, Mar. 1978, p. 191-194. Research supported by the Deutsche Forschungsgemeinschaft.

Physics

7

Atmospheric Chemistry, Hydroxyl Radicals, Ozone, Photolysis, Troposphere, Chemiluminescence, Gas Dissociation, Photodissociation, Temperature Effects

Scientific paper

The exact quantum yield of O (1D) formation from ozone photolysis in the UV range from 295 to 320 nm is important for aeronomic calculations, since O (1D) is the primary source for OH radicals in the troposphere. Recent O (1D) quantum-yield determinations at 230, 268, 298, and 320 K are summarized. An analytical expression is derived which relates the quantum yield of O (1D) formation as a function of wavelength and temperature.

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