Materials and fabrication processes for operation in hot hydrogen

Statistics – Applications

Scientific paper

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Spaceborne And Space Research Instruments, Apparatus, And Components

Scientific paper

Operation in hot (2500-3000 K) hydrogen severely limits the choice of structural materials. Rhenium is nonreactive with and has low permeability to hydrogen, and has sufficient strength up to 2800 K. Carbon, in the form of graphite or carbon composites, has excellent high temperature strength but reacts with hydrogen to form methane at a rapid rate above 2000 K. The carbides of zirconium, niobium, hafnium, and tantalum are nonreactive with and have low permeability to hydrogen, but they can be reliably fabricated only in the form of coatings. In order to demonstrate the Integrated Solar Upper Stage (ISUS) solar-thermal propulsion concept, rhenium and rhenium-coated graphite were chosen as the structural materials for the receiver-absorber-converter (RAC) component of the ISUS system. Several methods were investigated for fabricating the rhenium parts and coatings, with chemical vapor deposition (CVD) and Ultramet chosen as the most likely process and company for success. The CVD or rhenium and other refractory materials were thus applied to the ISUS program for fabrication of the RAC subsystem.

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