Mass transfer in two-phase nondispersing liquid-liquid contactors with a high-density-difference system

Physics

Scientific paper

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Contactors, Electrolytes, Liquid-Liquid Interfaces, Mass Transfer, Mercury (Metal), Polarography, Quinoline, Viscosity

Scientific paper

Mass transfer rates of an electrolyte through a turbulent aqueous film in an agitated two-phase nondispersing liquid-liquid contactor were measured using an aqueous electrolyte solution as the light phase and mercury as the heavy phase. The mass transfer rates were measured polarographically via the diffusion-limited, electrically driven reduction of quinone at the mercury surface in the contactor. The parameters proven to be most significant to the mass transfer rate were agitator speed, agitator diameter, and aqueous-phase viscosity. The correlation developed a new form of the intercept term which correlates mass transfer data over a much wider range of Sherwood numbers than that found in the literature.

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