Physics
Scientific paper
Jun 2010
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..conferg06w&link_type=abstract
"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec
Physics
Mini-Symposium: Metal Containing Molecules
Scientific paper
Lanthanum oxide, LaO2, is produced in a pulsed laser-vaporization metal-cluster source and studied by mass-analyzed threshold ionization (MATI) spectroscopy. From the MATI spectrum, the adiabatic ionization energy of LaO2 is determined to be 40134 (5) Cm-1 or 4.976 (6) eV, and La+-O stretching and O-La+-O bending frequencies are measured as 656 and 120 Cm-1. The measured ionization energy is about 3.0 eV lower than the value predicted by recent high-level ab initio calculations. In this talk, we will discuss the discrepancy between the experiment and theory and the electronic transition observed in our experiment.
T. K. Todorova, I. Infante, L. Gagliardi, and J. M. Dyke, J. Phys. Chem. A 112, 7825 (2008).
Krasnokutski Sergiy
Wu Lu
Yang Dong-Sheng
Zhang Chang-hua
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