Mapping the Evolution of Optically-Generated Rotational Wavepackets in a Room Temperature Ensemble of D$_2$

Physics – Quantum Physics

Scientific paper

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4 pages, 3 figures. Accepted for publication in Phys. Rev. A. Full reference to follow..

Scientific paper

10.1103/PhysRevA.76.023414

A coherent superposition of rotational states in D$_2$ has been excited by nonresonant ultrafast (12 femtosecond) intense (2 $\times$ 10$^{14}$ Wcm$^{-2}$) 800 nm laser pulses leading to impulsive dynamic alignment. Field-free evolution of this rotational wavepacket has been mapped to high temporal resolution by a time-delayed pulse, initiating rapid double ionization, which is highly sensitive to the angle of orientation of the molecular axis with respect to the polarization direction, $\theta$. The detailed fractional revivals of the neutral D$_2$ wavepacket as a function of $\theta$ and evolution time have been observed and modelled theoretically.

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