Magnetic dipole transitions in the hydrogen molecule

Physics

Scientific paper

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Electric And Magnetic Moments, Polarizability, And Magnetic Susceptibility, Electron Correlation Calculations For Diatomic Molecules, Atomic And Molecular Data, Spectra, And Spectral Parameters, Infrared Spectra

Scientific paper

In homonuclear molecules, such as H2, the electric dipole transitions are strongly forbidden, and the transitions between rovibrational states are of the electric quadrupole type. We show, however, that magnetic dipole transitions also take place, although they are significantly weaker. We evaluate the probabilities of such transitions between several of the lowest rotational states and compare them with those of the corresponding electric quadrupole transitions.

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