Physics
Scientific paper
Mar 2011
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011phrva..83c2501p&link_type=abstract
Physical Review A, vol. 83, Issue 3, id. 032501
Physics
Electric And Magnetic Moments, Polarizability, And Magnetic Susceptibility, Electron Correlation Calculations For Diatomic Molecules, Atomic And Molecular Data, Spectra, And Spectral Parameters, Infrared Spectra
Scientific paper
In homonuclear molecules, such as H2, the electric dipole transitions are strongly forbidden, and the transitions between rovibrational states are of the electric quadrupole type. We show, however, that magnetic dipole transitions also take place, although they are significantly weaker. We evaluate the probabilities of such transitions between several of the lowest rotational states and compare them with those of the corresponding electric quadrupole transitions.
Komasa Jacek
Pachucki Krzysztof
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