Low-density expansion for charged particles with hard cores

Details Low-density expansion for charged particles with hard cores Low-density expansion for charged particles with hard cores

Jun 2000

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2000aipc..519..223m&link_type=abstract

STATISTICAL PHYSICS: Third Tohwa University International Conference. AIP Conference Proceedings, Volume 519, pp. 223-225 (2000

Physics

Colloids, Gels And Sols, Thermodynamics Of Solutions

Scientific paper

Using field-theoretic methods, we obtain the low-density expansion of the free energy of systems where two ionic species with different valences (defined as the absolute value of the charge in units of e, here q1 and q2) and hard-core radii (d1 and d2) are present. The resulting expression (calculated up to order 5/2 in the concentration) is exact, and allows one to treat, in a unified way, electrolytes (where q1~q2 and d1~d2) and charged macro-particles suspensions (as for instance colloidal suspensions, where the size and the charge asymmetry are very large and play a crucial role). .

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