Long Range Proton-Migration in VUV Photoionization of Acetone Clusters

Physics

Scientific paper

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Infrared/Raman (Vibrational)

Scientific paper

Infrared spectroscopic investigations of neutral and cationic clusters
of acetone reveals proton-migraion for keto-enol tautomerization in
their ionization processes. In the reaction, the methyl proton of
acetone is transferred to its carbonyl oxygen through the intracluster
long range proton-migraion.

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