Long pathlength measurements of oxygen absorption cross sections in the wavelength region 205 - 240 nm.

Physics

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Uv Absorption:Molecular Oxygen

Scientific paper

New measurements of molecular oxygen photoabsorption cross sections and pressure coefficients have been made at room temperature in the wavelength region 205 - 240 nm of the Herzberg continuum. The experimental conditions [p(O2) < 100 Torr, pathlengths up to 1400 m] ensure accurate extrapolation to zero pressure of the pressure-dependent continuum cross sections. The results are in good agreement with recent laboratory data and are consistent with most of the stratospheric measurements. The O2 cross sections are found to be lower than values previously used in many photochemical stratospheric modelling calculations.

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