Liquid ternary aerosols of HNO3/H2SO4/H2O in the Arctic tropopause region

Physics

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Atmospheric Composition And Structure: Aerosols And Particles (0345, 4801), Atmospheric Composition And Structure: Cloud Physics And Chemistry, Atmospheric Composition And Structure: Middle Atmosphere-Composition And Chemistry

Scientific paper

Measurements of total reactive nitrogen (NOy) concentrations in the gas and aerosol phases were made on board the NASA DC-8 aircraft within 1 km above the Arctic tropopause in February 2000. As temperatures decreased, NOy was taken up into the background sulfate aerosols. The observed temperature-dependent NOy uptake agrees well with that calculated from a model of nitric acid (HNO3) uptake to form liquid HNO3/H2O/H2SO4 ternary droplets. The observations reported here provide the first direct evidence for the formation of ternary droplets in the Arctic tropopause region.

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