Line positions and strengths of HDO in the 2400-3300 per cm region

Details Line positions and strengths of HDO in the 2400-3300 per cm region Line positions and strengths of HDO in the 2400-3300 per cm region

Sep 1982

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1982apopt..21.3337t&link_type=abstract

Applied Optics, vol. 21, Sept. 15, 1982, p. 3337-3347. USAF-sponsored research;

Physics

Optics

34

Heavy Water, Infrared Spectra, Line Spectra, Molecular Spectra, Data Reduction, Least Squares Method, Rotational Spectra, Tables (Data)

Scientific paper

The vibration-rotation spectrum of HDO in the 2400-3300 per cm region has been studied at 0.01 per cm resolution with a Fourier transform spectrometer. Values of the ground state levels and levels in the (100) and (020) states have been determined from the data. The ground state levels are fitted to a Watson-type Hamiltonian from which 17 rotational constants are obtained. Measurements of the strengths of over 1100 lines have been made using a nonlinear least-squares fitting technique, and 548 of these lines are analyzed to determine the band strengths, the coefficients of the F factors, and the Coriolis interaction parameters. The strengths of the A- and B-type (100) bands and the A- and B-type (020) bands are 53.2 + or - 0.9, 0.43 + or - 0.07, 6.00 + or - 0.54, and 2.75 + or - 0.12 per sq cm per atm at 296 K, respectively.

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