Line frequency shifting in the ν5 band of C2H2.

Computer Science

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Acetylene: Laboratory Spectra, Acetylene: Infrared Spectra

Scientific paper

The pressure induced line frequency shifts of C2H2 in the ν5 band at 13.7 μm have been measured with N2, H2, Ar and He as buffer gases. The experiment used a diode laser which was frequency stabilized on the absorption peak of the studied line, and line shifts were determined by monitoring the laser frequency drifts vs. the gas pressure. Comparisons have been made with calculated results based on a semi-classical model including adjustable potential parameters.

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