Li$_5$ as a pseudorotating planar cluster

Details Li$_5$ as a pseudorotating planar cluster Li$_5$ as a pseudorotating planar cluster

1994-03-26

arxiv.org/abs/chem-ph/9403009v1

Physics

Chemical Physics

Physical Review A (in press). 4 pages + 3 postscript figures included. RevTeX and psfig

Scientific paper

10.1103/PhysRevA.49.4236

A pseudorotating state of Li$_5$ observed in a recent EPR experiment is
investigated using the local density functional method. The calculated
isotropic spin population indicates that a planar $C_{2v}$ structure is more
consistent with the experimental result than a suggested trigonal bipyramid. A
new pseudorotating state based on the planar structure is proposed.

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