Laboratory studies of UV emissions of H2 by electron impact - The Werner- and Lyman-band systems

Physics – General Physics

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Electron Impact, Fluorescence, Hydrogen, Lyman Spectra, Molecular Spectra, Ultraviolet Radiation, Molecular Excitation, Molecular Oscillations, Photomultiplier Tubes, Spectral Bands

Scientific paper

The vacuum ultraviolet electron-impact-induced fluorescence emissions of H2 were studied for the Lyman and Werner band systems in the range of 120-170 nm, using an optical system containing a photomultiplier and a spectrometer, over an energy range from threshold to 400 eV. The emission cross sections for the Lyman and Werner transitions at 100 eV are determined. The cross-section ratio is in excellent agreement with theoretical calculations and experimental data for the optical oscillator strengths. The cross-section for cascading to the B state is stated as a percentage of the total emission cross section at both 100 and 300 eV, increasing substantially at 20 eV. The vibrational population distribution of the B state is found to be a function of electron-impact energy as the importance of cascading relative to direct excitation changes with electron-impact energy.

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