Kinetics of the reaction of CH3O2 with ClO at 293 K

Details Kinetics of the reaction of CH3O2 with ClO at 293 K Kinetics of the reaction of CH3O2 with ClO at 293 K

Aug 1993

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1993georl..20.1571k&link_type=abstract

Geophysical Research Letters (ISSN 0094-8276), vol. 20, no. 15, p. 1571-1574.

Physics

9

Atmospheric Chemistry, Chlorides, Photolysis, Reaction Kinetics, Electron Energy, Ozone Depletion, Stratosphere

Scientific paper

A flow reactor sampled by a mass spectrometer is used to study the reaction of CH3O2 with ClO at 293 K. Under conditions where (ClO) is much greater than (CH3O2), the CH3O2 decayed under pseudo-first-order conditions, giving a rate coefficient of (1.9 +/- 0.4) x 10 exp -12 cu cm/s. CH3OCl was detected as a reaction product. The implications of the measurements for the chemistry of the stratosphere are discussed.

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