Kinetics and thermochemistry of polyatomic free radicals: new results and new understandings.

Physics

Scientific paper

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Scientific paper

An experimental facility for the study of the chemical kinetics of polyatomic free radicals is described which consists of a heatable tubular reactor coupled to a photoionization mass spectrometer. Its use in different kinds of chemical kinetic studies is also discussed. Examples presented include studies of the C2H3 + O2, C2H3 + HCl, CH3 + O, and CH3 + CH3 reactions.

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