Kinetic Spectroscopy in the Far Ultra-Violet: The Flash Photolysis of Ethyl Compounds

Physics

Scientific paper

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Scientific paper

An apparatus is described for the recording of the far u.v. absorption spectra of transient species produced by flash photolysis. Using lithium fluoride windows, observations can be made down to 1250 angstrom. The flash photolysis of mercury diethyl and lead tetraethyl yield appreciable amounts of the methyl radical, and it is thought that these are formed by reaction between ethyl radicals, one of which is excited.

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