Kinetic isotopic fractionation and the origin of HDO and CH3D in the solar system

Physics

Scientific paper

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Abundance, Deuterium, Fractionation, Heavy Water, Methane, Solar System, Photochemical Reactions, Planetary Atmospheres, Planetary Evolution, Stellar Evolution, Ultraviolet Radiation

Scientific paper

It is suggested that photochemical enrichment processes driven by stellar UV emissions could result in a large deuterium fractionation of water and methane relative to H2 in the primitive solar nebula. These enrichment processes could have profoundly influenced the isotopic content of water in the terrestrial planets, if a large fraction of their volatiles had been added by impacts of meteorites and comets formed in the outer parts of the solar nebula. Efficient mixing could have exposed the material in the interior of the solar nebula to starlight.

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