K, Rb, Cs and Sr relationships in submarine basalts from the Puerto Rico trench

Physics

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Scientific paper

Basalts dredged from a restricted region on the north wall of the Puerto Rico trench show a wide range in K (620-5600 ppm), K / Rb (430-2030), K / Cs (4560/81,000) and K / Sr (6.8-35.7). There is a positive correlation between K, K / Rb , K / Cs , K / Sr , Sr and SiO 2 . Deuteric or sea water alteration of these basalts is suggested by high H 2 O + contents and Fe 2 O 3 / FeO ratios. If Sr 87 / Sr 86 ratios as high as 0.706 are taken as evidence of sea water alteration, then it follows that such alteration processes may produce the observed positive trends of K / Rb and K / Cs versus K content. The extreme freshness required for meaningful trace element analysis or K-Ar dating of submarine basalts is emphasized by these results.

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