JNO2 at high solar zenith angles in the lower stratosphere

Physics

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Atmospheric Composition And Structure: Chemical Kinetic And Photochemical Properties, Atmospheric Composition And Structure: Middle Atmosphere-Composition And Chemistry, Electromagnetics: Scattering And Diffraction

Scientific paper

In situ measurements of NO, NO2, O3, HO2, ClO, pressure, and temperature have been made at high solar zenith angles (SZA, 70°-93°) in the lower stratosphere. These measurements are used to derive the photolysis rate of NO2, JNO2, using a time-dependent method. The resultant JNO2 values and the results of a multiple-scattering actinic flux model show a linear relationship throughout the SZA range. The difference of the two sets of JNO2 values of about 11% suggests that the model scattering calculation is very accurate at high SZA conditions near sunrise and sunset.

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