J-dependence of the lineshift coefficients in the ν2 water vapor band.

Physics

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Water Vapor: Laboratory Spectra, Water Vapor: Infrared Spectra

Scientific paper

The nitrogen pressure shifting coefficients for the 150 water vapor lines in the ν2 band have been measured with the Fourier transform spectrometer located at the Paris VI University with the spectral resolution of 0.005 cm-1 and at room temperature. The measurements were performed for lines having lower state angular moment up to 16, the measured values are found to range from +0.015 to -0.0293 cm-1/atm. The J-dependence of the line shift coefficients was studied using the Anderson-Tsao-Curnutte model and cut-of-free method. Fairly satisfactory agreement between measured and calculated line shift coefficients has been found.

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