Isotopic ozone in the 5 μ region from high resolution balloon-borne and ground-based FTIR solar spectra.

Physics

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Earth Atmosphere: Infrared Spectra, Earth Atmosphere: Absorption Spectra, Earth Atmosphere: Ozone

Scientific paper

High resolution (0.002-0.004 cm-1) i.r. solar absorption spectra of the stratosphere obtained during University of Denver balloon flights, and from the ground-based Network for the Detection of Stratospheric Change (NDSC) observatory at Mauna Loa, Hawaii, show numerous spectral features of several isotopic species of O3, in both the 10 μ and 5 μ regions. Many of the 5 μ lines reported here have not been previously observed in atmospheric spectra. The identification and quantification of the lines proceed by combined analyses of the atmospheric spectra, laboratory spectra of enriched samples, and updated line parameter calculations.

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