Isotopic measurements of stratospheric ozone

Details Isotopic measurements of stratospheric ozone Isotopic measurements of stratospheric ozone

Sep 2000

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2000georl..27.2593k&link_type=abstract

Geophysical Research Letters, Volume 27, Issue 17, p. 2593-2596

Physics

36

Atmospheric Composition And Structure, Atmospheric Composition And Structure: Middle Atmosphere-Composition And Chemistry, Atmospheric Composition And Structure: Middle Atmosphere-Constituent Transport And Chemistry

Scientific paper

Isotope ratios of stratospheric ozone samples collected during four balloon flights are reported. In an altitude range between 22 and 33 km all ratios show enrichments between 7 and 11%, somewhat lower for 49O3 than for 50O3. Those enrichments are in very good agreement with results from laboratory isotope studies when stratospheric pressure and temperatures are included. The new data presented do raise questions about past stratospheric ozone isotope measurements which sometimes showed high values never observed in the laboratory or tropospheric environment.

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