Isolation of degraded pentacyclic triterpenoid acids in a Nigerian crude oil and their identification as tetracyclic carboxylic acids resulting from ring A cleavage

Physics

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Scientific paper

Three tetracyclic acids were identified in a Nigerian crude oil, after reduction and deuterium labelling followed by GC/MS investigation. Two of them are identical to 3:4 seco acids previously identified in sediments. The third one is a novel C 24 acid that has not been reported up to now. These geochemical markers are assumed to belong to the class of photochemical tetracyclic triterpenes formed by decay of pentacyclic 3-ketoterpenoids.

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